[PDF]  https://doi.org/10.3952/physics.v60i1.4166

Open access article / Atviros prieigos straipsnis
Lith. J. Phys. 60, 78–89 (2020)
 

HYBRID ORGANIC-INORGANIC Fe3O(TFBDC)3(H2O)3·(DMF)3 COMPOUND SYNTHESIZED BY SLOW EVAPORATION METHOD: CHARACTERIZATION AND COMPARISON OF MAGNETIC PROPERTIES
  Andrius Laurikėnasb, Kęstutis Mažeikab, Dalis Baltrūnasa, Ramūnas Skaudžiusa, Aldona Beganskienėa, and Aivaras Kareivaa
 aInstitute of Chemistry, Vilnius University, Naugarduko 24, 03225 Vilnius, Lithuania
bCenter for Physical Sciences and Technology, Savanorių 231, 02300 Vilnius, Lithuania
Email: aivaras.kareiva@chgf.vu.lt

Received 19 October 2019; revised 26 October 2019; accepted 4 November 2019

In this study for the synthesis of a hybrid organic-inorganic Fe3O(TFBDC)3(H2O)3·(DMF)3 compound a slow evaporation method has been suggested. THe synthesis product was characterized using X-ray powder diffraction (XRD) analysis, scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) coupled with SEM and electron paramagnetic resonance (EPR) spectroscopy. THe antiferromagnetic/weakly ferromagnetic behaviour of the synthesized sample was confirmed by magnetization measurements and Mössbauer spectroscopy. THe synthesized magnetic material could be itself tested for different medical applications and could be used as precursor material for the preparation of nanostructured iron oxides with a variety of useful properties for biomedicine.
Keywords: hybrid materials, organic-inorganic, iron, slow evaporation method, magnetic properties
PACS: 75.50.–y, 75.60.Ej, 76.80.+y, 81.05.–t, 81.20–n


HIBRIDINIO ORGANINIO-NEORGANINIO Fe3O(TFBDC)3(H2O)3·(DMF)3 JUNGINIO SINTEZĖ LĖTO GARINIMO METODU. APIBŪDINIMAS IR MAGNETINIŲ SAVYBIŲ PALYGINIMAS
    Andrius Laurikėnasb, Kęstutis Mažeikab, Dalis Baltrūnasa, Ramūnas Skaudžiusa, Aldona Beganskienėa, Aivaras Kareivaa

aVilniaus universiteto Chemijos institutas, Vilnius, Lietuva
bFizinių ir technologijos mokslų centras, Vilnius, Lietuva
 
Lėto garinimo metodu susintetintas hibridinis organinis-neorganinis Fe3O(TFBDC)3(H2O)3·(DMF)3 junginys. Susintetintas naujas junginys buvo apibūdintas rentgeno spindulių difrakcinės (XRD) analizės, skenuojančios elektroninės mikroskopijos (SEM), energijos dispersinės rentgeno spindulių spektroskopijos (EDX) ir paramagnetinio rezonanso spektroskopijos (EPR) metodais. Susintetinto mėginio antiferomagnetinė / silpnai feromagnetinė reakcija buvo patvirtinta magnetėjimo ir Mössbauerio spektroskopijos tyrimų rezultatais. Susintetinta magnetinė medžiaga gali būti tiriama medicininiams tikslams ir panaudota kaip pirmtakas nanostruktūrinto geležies oksido sintezei.

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